Hi Cecilia,
By saying 64bit i am guessing that your processor will be x64 and not Itanium.
If my assumptions are correct, then there will be no issues to look into since both editions of SQL Server uses the same on-disk structures which means you can simply detach your database from a 32 bit platform and attach it to an x64 platform. You don't need to change anything else... On the database and on the application level that is. On the server level, there are a few settings that you need to configure properly like processor affinity, memory utilization and so on. Remember that this time around, you are no longer limited to 4Gb addressable ram.
If you are upgrading to Itanium however, please note that Business Intelligence Development Studio does not run on Itanium. Which means that you cannot create BIDS project in your Itanium server which by right, you should be really doing dev on a prod environment...
HTH